PHOTOCHEMISTRY OF ETHENOBENZOCYCLOHEPTENONES. A DI-?-METHANE REARRANGEMENT OF β,γ-UNSATURATED ARYL KETONES

DOI: 10.1016/0040-4020(82)85089-8

Source and publish data:

Tetrahedron p. 2539 - 2546 (1982)

Update date:2022-08-03

Topics:

Authors:

Hassner, Alfred

Middlemiss, David

Murray-Rust, Judith

Murray-Rust, Peter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(82)85089-8

Benzotropones 6 react with dienophiles 7 to give endo-adducts 8 as shown by PMR.Unlike similar ketones which usually undergo 1,3-acyl shifts or oxadi-?-methane rearrangements, these ethenobenzocycloheptenones 8, on direct or sensitized irradiation, lead t

Full text of DOI:10.1016/0040-4020(82)85089-8

Products guided by the article

Product name:2,2a,2b,7,7a,7b-hexahydro-7-oxo-N-phenyl-1H-benzocyclopropindene-1,2-dicarboximide

Cas No:84574-63-0

R&D Labs maybe for 84574-63-0

ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
GBXF SILICONES CO.,LTD

website:http://www.gbxfsilicones.com/

Contact:86-25-68900673

Address:He Country Provincial Fine Chemical Industrial Park of Chaohu city,Anhui province,China

Relevant to this article

THE CHEMICAL SYNTHESIS OF THE R_p AND S_p DIASTEREOMERS OF THYMIDYL-(3'-5')THYMIDYL O,O-PHOSPHOROTHIOATE

Doi:10.1016/S0040-4039(00)88727-4
(1982)
PERMANGANATE OXIDATION OF 3-METHYL-4-NITRO-5-STYRILISOXAZOLE:A CORRECTION

Doi:10.1016/S0040-4039(00)85611-7
(1982)
A chemical approach for cell-specific targeting of nanomaterials: Small-molecule-initiated misfolding of nanoparticle corona proteins

Doi:10.1021/ja300537u
(2012)
Synthesis of 5-phenyl-5,6,7,8-tetrahydro-1,6-naphthyridines and 5-phenyl-6,7,8,9-tetrahydro-5H-pyrido[3,2-c]azepines as potential D1 receptor ligands

Doi:10.1002/jhet.5570410602
(2004)
Cyclic depsipeptides, grassypeptolides D and e and Ibu- epidemethoxylyngbyastatin 3, from a Red Sea Leptolyngbya cyanobacterium

Doi:10.1021/np200270d
(2011)
Organic Redox Systems Based on Pyridinium-Carbene Hybrids

Doi:10.1021/jacs.9b04249
(2019)

Article Doi