Journal of the Chemical Society. Chemical communications p. 932 - 933 (1982)
Update date:2022-08-04
Topics:
Chatt, Joseph
Hitchcock, Peter B.
Pidcock, Alan
Warrens, Christopher P.
Dixon, Keith R.
The structure of a new and potentially general synthesis, is essentially planar with only a 3 deg twist between the two PdP2 planes and a P-P bond distance of 2.121(4) Angstrom; 31P n.m.r. data on the analogous platinum complexes show very small s-character in the Pt-P(diphosphene) bonds, suggesting that the structure is essentially a diphosphene bound to Pt0 rather than that of a diphosphido(2-) ligand bound to PtII.
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(1989)
