DIASTEREOSELECTION IN 1,3-O- TO -C-ALKYL MIGRATION REACTION OF 1-ALKENYL ALKYL ACETALS CATALYZED BY BORON TRIFLUORIDE ETHERATE

DOI: 10.1016/S0040-4039(00)88688-8

Source and publish data:

Tetrahedron Letters p. 4031 - 4034 (1982)

Update date:2022-08-03

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Authors:

Takahashi, Mitsuru

Suzuki, Hiroharu

Moro-Oka, Yoshihiko

Ikawa, Tsuneo

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Article abstract of DOI:10.1016/S0040-4039(00)88688-8

Remarkable diastereoselection, with (E)-alkenyl alkyl acetal giving selectively the erythro α-alkyl-β-alkoxyaldehyde, and (Z)-acetal leading preferentially to the threo isomer, is observed in the 1,3-O- to -C-alkyl migration reaction of 1-alkenyl alkyl ac

Full text of DOI:10.1016/S0040-4039(00)88688-8

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