Chemistry - A European Journal p. 939 - 944 (2005)
Update date:2022-08-03
Topics:
Roussel, Solveig
Billard, Thierry
Langlois, Bernard R.
Saint-James, Laurent
Various trifluoroacetamides and trifluoromethanesulfinamides, derived from chiral silylated amino alcohols, have been synthesized with the goal of achieving enantioselective nucleophilic trifluoromethylation. The best results were obtained with (R)-phenylglycinol derivatives, but the ee values did not exceed 30%.
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