A unique approach to metal-induced Bergman cyclization: Long-range enediyne activation by ligand-to-metal charge transfer

DOI: 10.1002/anie.200461825

Source and publish data:

Angewandte Chemie - International Edition p. 592 - 595 (2005)

Update date:2022-08-04

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Authors:

Bhattacharyya, Sibaprasad

Pink, Maren

Baik, Mu-Hyun

Zaleski, Jeffrey M.

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Article abstract of DOI:10.1002/anie.200461825

Dramatic differences are found in the temperatures at which Bergman cyclizations occur when Mo^IV-enedithiolate-enediyne complexes are used (see scheme; S: yellow, Mo: red), and this can be directly attributed to a long-range electronic polariza

Full text of DOI:10.1002/anie.200461825

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