Journal of Organic Chemistry p. 3394 - 3396 (1986)
Update date:2022-07-29
Topics:
Brown, Herbert C.
Chandrasekharan, J.
Ramachandran, P. V.
(-)-Diisopinocampheylchloroborane, which reduces many aralkyl and heteroaralkyl ketones with remarkably high stereoselectivity, has now been found to reduce α-tertiary alkyl ketones with similar high enantiomeric excess.Such ketones have resisted asymmetr
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