Stereoselective glycosylation of d-galactals by diethyl phosphorochloridite- and AlCl3-assisted Ferrier rearrangement

DOI: 10.1016/j.tet.2014.11.027

Source and publish data:

Tetrahedron p. 350 - 358 (2015)

Update date:2022-09-26

Topics:

Authors:

Chen, Yen-Bo

Wang, Su-I.

Lin, Zi-Ping

Lin, Chun-Hung

Hsieh, Min-Tsang

Lin, Hui-Chang

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Article abstract of DOI:10.1016/j.tet.2014.11.027

α-2,3-Unsaturated galactosides were synthesized in good to excellent yields by the initial activation of d-galactals with diethyl phosphorochloridite and the subsequent glycosyl addition via Ferrier rearrangement with various O-nucleophiles in the presenc

Full text of DOI:10.1016/j.tet.2014.11.027

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