Tetrahedron p. 103 - 110 (1992)
Update date:2022-07-31
Topics:
Farkas, Frederic
Sequin, Urs
Bur, Daniel
Zehnder, Margareta
The reaction of trans-diepoxycyclopentane with azide leads in methanol to the expected azidohydrins; a 1,4-adduct with a 'central' epoxy group is also formed. When the reaction is carried out in acetone/water 1:1, an additional product, which is the acetonide of an azido-trihydoxycyclopentane, is observed. This compound must have been formed by participation of the solvent followed by cyclization.
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