Carbanion Photochemistry. 7. The SRN1 vs. SET Photoarylation of Triphenylmethyl Anion

DOI: 10.1021/jo00156a008

Source and publish data:

Journal of Organic Chemistry p. 1185 - 1190 (1983)

Update date:2022-07-31

Topics:

Authors:

Tolbert, Laren M.

Martone, Daniel P.

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Article abstract of DOI:10.1021/jo00156a008

Irradiation of (triphenylmethyl)lithium in tetrahydrofuran containing bromobenzene, iodobenzene, or diphenyl sulfoxide produced three major products: tetraphenylmethane (TPM), biphenylyldiphenylmethane (BDM), and 2-(triphenylmethyl)tetrahydrofuran (TTF).The product composition was a function of anion and acceptor concentration and reflected the competition among solvent, triphenylmethyl anion, and triphenylmethyl radical.Product composition studies thus provide detailed information about the key steps in the mechanism.

Full text of DOI:10.1021/jo00156a008

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