Journal of Organic Chemistry p. 1185 - 1190 (1983)
Update date:2022-07-31
Topics:
Tolbert, Laren M.
Martone, Daniel P.
Irradiation of (triphenylmethyl)lithium in tetrahydrofuran containing bromobenzene, iodobenzene, or diphenyl sulfoxide produced three major products: tetraphenylmethane (TPM), biphenylyldiphenylmethane (BDM), and 2-(triphenylmethyl)tetrahydrofuran (TTF).The product composition was a function of anion and acceptor concentration and reflected the competition among solvent, triphenylmethyl anion, and triphenylmethyl radical.Product composition studies thus provide detailed information about the key steps in the mechanism.
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