REDUCTIVE TRANSFORMATIONS 2. CIS- AND TRANS-1,2-ADDITION OF ELECTROPHILES TO DIANIONIC ?-SYSTEMS

DOI: 10.1016/S0040-4039(00)87735-7

Source and publish data:

Tetrahedron Letters p. 3889 - 3892 (1982)

Update date:2022-07-29

Topics:

Authors:

Huber, W.

Irmen, W.

Lex, J. Lex, J.

Muellen, K.

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Article abstract of DOI:10.1016/S0040-4039(00)87735-7

The dianion salt of a polycyclic ?-system is selectively alkylated to yield <14>annulenes with trans- or cis-configuration of the bridging group.The products are suitable models for spectroscopic and structural considerations.

Full text of DOI:10.1016/S0040-4039(00)87735-7

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