Journal of Organic Chemistry p. 1293 - 1297 (1983)
Update date:2022-09-26
Topics:
Tamaru, Yoshinao
Yoshida, Zen-ichi
Yamada, Yoshimi
Mukai, Kunio
Yoshioka, Hirosuke
The thiono-thiolo allylic rearrangement of O-allyl phosphoro- and phosphonothionates is effected by catalysis with Pd(0).A wide variety of O-allyl thionates (17 kinds) are rearranged selectively to the thermodynamically more stable regio- and stereoisomers via a (?-allyl)palladium intermediate.Thermal rearrangement of α- and γ-methallyl diethyl phosphorothionates is reinvestigated in relation to the regioselectivity observed in the palladium(0) catalysis.
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(1982)
