Journal of Organic Chemistry p. 3426 - 3439 (2020)
Update date:2022-08-04
Topics:
Paul, Amrita
Shah, Sk. Sheriff
Shee, Maniklal
Singh, Amit Kumar
Singh, N. D. Pradeep
This report presents the oxygenation of C-H bonds via the merger of photocatalysis and Pd catalysis. Herein, we describe the utilization of a photocatalyst to oxidize an organopalladium(II) intermediate to high-valent PdIII or PdIV intermediates, which promotes the formation of C-O bonds. The demonstrated method works efficiently with various directing groups, such as oxime ether and benzothiazole. The applicability of this direct C-O bond formation method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that can be used in organic light-emitting diodes and pharmaceuticals.
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Doi:10.1039/c4ra05206d
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(2014)Doi:10.1134/S1070363214030098
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(2014)Doi:10.1016/j.ejmech.2014.03.046
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