Reductive Elimination of Vicinal Oxygen Functions with Palladium(0). Applications in the Withanolide Series

DOI: 10.1021/jo00163a025

Source and publish data:

Journal of Organic Chemistry p. 2550 - 2555 (1983)

Update date:2022-08-05

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Authors:

Keinan, Ehud

Sahai, Mahendra

Kirson, Isaac

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Article abstract of DOI:10.1021/jo00163a025

A high-yielding, chemoselective approach to the steroidal 6β-hydroxy 2,4-dien-1-one system is described by starting from the 4β-acetoxy-5β,6β-epoxy 2-en-1-one derivative.The method allows some useful interconversions in the withanolide series such as the

Full text of DOI:10.1021/jo00163a025

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