PALLADIUM-PROMOTED TRANSFORMATION OF α,β-EPOXYSILANES TO α,β-UNSATURATED CARBONYL COMPOUNDS

DOI: 10.1246/cl.1982.1997

Source and publish data:

Chemistry Letters p. 1997 - 2000 (1982)

Update date:2022-07-30

Topics:

Authors:

Hirao, Toshikazu

Yamada, Naoto

Ohshiro, Yoshiki

Agawa, Toshio

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Article abstract of DOI:10.1246/cl.1982.1997

Treatment of α,β-epoxysilanes with palladium(II) salt in DMF affords α,β-unsaturated carbonyl compounds, in which the carbonyl group appears on the carbon originally bearing the silylgroup.

Full text of DOI:10.1246/cl.1982.1997

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