Dimerization Mechanism of the 1-Alkyl-4-phenylpyridinyl Radicals Generated from the Photosensitive Dimer As Studied by Kinetic ESR Spectroscopy

DOI: 10.1021/ja00349a041

Source and publish data:

Journal of the American Chemical Society p. 3601 - 3604 (1983)

Update date:2022-09-26

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Authors:

Akiyama, Kimio

Tero-Kubota, Shozo

Ikegami, Yusaku

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Article abstract of DOI:10.1021/ja00349a041

The dimerization mechanism of 1-methyl- (1), 1-ethyl- (2), and 1-isopropyl-4-phenylpyridinyl (3) radicals is discussed on the basis of the kinetic and thermodynamic studies.Absolute rate constants for dimerization are determined from the ESR decay curves

Full text of DOI:10.1021/ja00349a041

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