Journal of Organic Chemistry p. 1670 - 1678 (1983)
Update date:2022-08-03
Topics:
House, Herbert O.
Gaa, Peter, C.
Lee, Joseph H. C.
VanDerveer, Don
The four diastereoisomeric 6-tert-butyl-4-oxoperhydroazulenes (3-6) have been prepared and characterized.Molecular mechanics calculations suggest that each of these ketones will exist as one or both of a pair of closely related conformers as follows: 3, C-3 or TC-7; 4, TC-1 or TC-2; 5, B-3 or TB-4; 6, TC-4 or TC-5.A combination of 1H NMR data and X-ray crystallographic data support the correctness of these predictions.
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Doi:10.1002/chem.200401223
(2005)Doi:10.3390/10010201
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(1992)
