4-Chloro-2-lithio-1-butene, a Novel Donor-Acceptor Conjunctive Reagent

DOI: 10.1021/jo00158a040

Source and publish data:

Journal of Organic Chemistry p. 1774 - 1776 (1983)

Update date:2022-08-04

Topics:

Authors:

Piers, Edward

Karunaratne, Veranja

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Article abstract of DOI:10.1021/jo00158a040

Transmetalation of 4-chloro-2-(trimethylstannyl)-1-butene (10) provides 4-chloro-2-lithio-1-butene (11), which reacts smoothly at -78 deg C with aldehydes, ketones, and α,β-unsaturated N,N',N'-trimethylhydrazides to produce, after warming of the resultant

Full text of DOI:10.1021/jo00158a040

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