Palladium-catalyzed asymmetric synthesis of axially chiral molecules

DOI: 10.1016/0022-328X(89)87300-0

Source and publish data:

Journal of Organometallic Chemistry p. 383 - 396 (1989)

Update date:2022-08-03

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Authors:

Fiaud, J. C.

Legros, J. Y.

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Article abstract of DOI:10.1016/0022-328X(89)87300-0

The asymmetric synthesis of chiral 3-alkylidene bicyclo<3.3.0>octane and 4-substituted 1-alkylidene cyclohexane systems has been carried out (in up to 40percent ee) by the palladium-catalyzed reaction of allylic acetates with sodium dimethyl malonate or m

Full text of DOI:10.1016/0022-328X(89)87300-0

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