7&α- or 7&β-(4-Phenylbutyl)dihydrocodeine Derivatives

DOI: 10.1021/jo00159a005

Source and publish data:

Journal of Organic Chemistry p. 1813 - 1819 (1983)

Update date:2022-07-29

Topics:

Authors:

Leland, David L.

Kotick, Michael P.

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Article abstract of DOI:10.1021/jo00159a005

A lipophilic 4-phenylbutyl group was selectively incorporated into the 7α- or 7β-position of the morphine nucleus by use of 6,7-oxymethylene (oxetane) intermediates. 7,7-Bis<(tosyloxy)methyl>dihydroisocodeine (2) with dilute NaOH gave 6β,7β-(oxymethylene)

Full text of DOI:10.1021/jo00159a005

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