Tetrahedron Letters p. 4781 - 4784 (1982)
Update date:2022-08-03
Topics:
Oppolzer, Wolfgang
Chapuis, Christian
Dao, Guo Mao
Reichlin, Daniel
Godel, Thierry
Starting from (R)-(+)- and from (S)-(-)-camphor the chiral alcohols 1, 2 and 3 have been prepared; their acrylates II underwent TiCl2(OR)2-promoted Diels-Alder additions to cyclopentadiene giving efficiently in a predictable manner either the (2R)- or the (2S)-adducts III with up to virtually quantitative asymmetric induction.
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Doi:10.1039/jr9500002096
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(2005)Doi:10.1021/ja01365a046
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(1983)
