Erratum: Ruthenium-catalyzed C-H hydroxylation in aqueous acid enables selective functionalization of amine derivatives (Journal of the American Chemical Society (2017) 139:28 (9503-9506) DOI: 10.1021/jacs.7b05469)

Article abstract of DOI:10.1021/jacs.1c00564

Page 9504. The structure of product 3cc in Table 2 was found to be mis-assigned. We thank Prof. Phil Baran and Dr. Rafael Navratil for bringing this error to our attention. The correct structure contains an additional benzylic alcohol at the C-9 position of the steroid (3cc′, shown below). With the accompanying change in molecular weight, the isolated yield is 29%. Supporting Information. The incorrect structure and yield also appeared on pages S20 and S84 in the SI. Given this, the HRMS entry on page S20 should read as follows: “HRMS (ESI-TOF) m/z calcd for C₁₉H₁₈F₃O₅S⁺ (M-O+Na)⁺ 415.0822, found 415.0857”. The complete corrected SI is provided here.

Full text of DOI:10.1021/jacs.1c00564

pubs.acs.org/JACS
Addition/Correction
Correction to “Ruthenium-Catalyzed C−H Hydroxylation in Aqueous
Acid Enables Selective Functionalization of Amine Derivatives”
James B. C. Mack, John D. Gipson, J. Du Bois,* and Matthew S. Sigman*
J. Am. Chem. Soc. 2017, 139 (28), 9503−9506. DOI: 10.1021/jacs.7b05469
Cite This: J. Am. Chem. Soc. 2021, 143, 3016−3016
Read Online
sı
*
Metrics & More
Article Recommendations
Supporting Information
ACCESS
Page 9504. The structure of product 3cc in Table 2 was found
to be mis-assigned. We thank Prof. Phil Baran and Dr. Rafael
Navratil for bringing this error to our attention. The correct
structure contains an additional benzylic alcohol at the C-9
position of the steroid (3cc′, shown below). With the
accompanying change in molecular weight, the isolated yield
is 29%.
Supporting Information. The incorrect structure and yield
also appeared on pages S20 and S84 in the SI. Given this, the
HRMS entry on page S20 should read as follows: “HRMS
(ESI-TOF) m/z calcd for C19H18F3O5S+ (M−O+Na)+
415.0822, found 415.0857”. The complete corrected SI is
provided here.
ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge at
https://pubs.acs.org/doi/10.1021/jacs.1c00564.
■
sı
Experimental details (corrected) (PDF)
Published: February 11, 2021
https://dx.doi.org/10.1021/jacs.1c00564
J. Am. Chem. Soc. 2021, 143, 3016−3016
© 2021 American Chemical Society
3016