Journal of Organic Chemistry p. 2294 - 2295 (1983)
Update date:2022-08-02
Topics:
Elliott, John D.
Choi, Vanessa M. F.
Johnson, William S.
The titanium tetrachloride catalyzed reaction of the 2(R),4-(R)pentanediol acetals 1a-c with cyanotrimethylsilane proceeds in excellent yield and high diastereoselectivity to give cyanohydrin ethers 3a-c, and conditions have been developed for conversion of these ethers into cyanohydrins, β-amino alcohols and α-hydroxy esters with optical purities of greater then 90 percent.
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(1933)
