THE METHOXYCARBONYLALKYLATION AND METHOXYCARBONYLALKYLIDENATION OF SILYL ENOL ETHERS

DOI: 10.1016/S0040-4039(00)81397-0

Source and publish data:

Tetrahedron Letters p. 327 - 328 (1983)

Update date:2022-08-04

Topics:

Authors:

Fleming, Ian

Iqbal, Javed

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81397-0

Silyl enol ethers (1) react with the phenylthio(methoxycarbonyl)alkyl chlorides (2) in the presence of Lewis acids to give good yields of the γ-ketoesters (3); oxidative and reductive desulphurisations give the saturated (4) and unsaturated (5 or 6) γ-ket

Full text of DOI:10.1016/S0040-4039(00)81397-0

Products guided by the article

Product name:2-Chloro-2-phenylsulfanyl-butyric acid methyl ester

Cas No:86044-08-8

R&D Labs maybe for 86044-08-8

KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Airsea(Taizhou) Pharmaceutical Limited(expird)

Contact:+86-576-88057622

Address:Dubei, Duqiao, Linhai, Taizhou, Zhejiang, China Zip: 317016
Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
WUHAN RISON TRADING CO.,LTD

Contact:0086-27-83607103/83642615

Address:No.498, Jianshe Ave, Wuhan, China

Relevant to this article

A facile synthesis of substituted 3-amino-1H-quinazoline-2,4-diones

Doi:10.1002/jhet.5570420428
(2005)
Br?nsted Acid-Catalyzed Intramolecular Nucleophilic Substitution of the Hydroxyl Group in Stereogenic Alcohols with Chirality Transfer

Doi:10.1021/jacs.5b02013
(2015)
Studies toward the synthesis of azadirachtin, part 2: Construction of fully functionalized ABCD ring frameworks and unusual intramolecular reactions induced by close-proximity effects

Doi:10.1002/anie.200500217
(2005)
Rearrangement of acyloxyoxiranes: A revised structure for the oxidation product of 5α-androst-16-ene-3α,17-diol 3-benzoate 17-acetate

Doi:10.1016/S0040-4020(01)89038-4
(1992)
Tetradentate diamido-bis-sulfide ligands on the base of o-aminobenzenethiol and their complexation with NiII, CoII, CuII chlorides in DMF solution and on the gold electrode surface

Doi:10.1007/s11172-009-0236-7
(2009)
Silane@TiO₂ nanoparticles-driven expeditious synthesis of biologically active benzo[4,5]imidazo[1,2-a]chromeno[4,3-d]pyrimidin-6-one scaffolds: A green approach

Doi:10.1007/s12039-016-1060-x
(2016)

Article Doi