THE METHOXYCARBONYLALKYLATION AND METHOXYCARBONYLALKYLIDENATION OF SILYL ENOL ETHERS

DOI: 10.1016/S0040-4039(00)81397-0

Source and publish data:

Tetrahedron Letters p. 327 - 328 (1983)

Update date:2022-08-04

Topics:

Authors:

Fleming, Ian

Iqbal, Javed

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Article abstract of DOI:10.1016/S0040-4039(00)81397-0

Silyl enol ethers (1) react with the phenylthio(methoxycarbonyl)alkyl chlorides (2) in the presence of Lewis acids to give good yields of the γ-ketoesters (3); oxidative and reductive desulphurisations give the saturated (4) and unsaturated (5 or 6) γ-ket

Full text of DOI:10.1016/S0040-4039(00)81397-0

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