Asymmetric construction of quaternary carbon stereocenters: High stereoselection in Mukaiyama aldol reactions of 2-siloxyindoles with chiral aldehydes

DOI: 10.1021/ol051172+

Source and publish data:

Organic Letters p. 2795 - 2797 (2005)

Update date:2022-07-29

Topics:

Authors:

Adhikari, Susanta

Caille, Sebastien

Hanbauer, Martin

Ngo, Vinh X.

Overman, Larry E.

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Article abstract of DOI:10.1021/ol051172+

(Chemical Equation Presented) A new synthesis of enantiopure 3,3-disubstituted oxindoles by stereoselective Mukaiyama aldol reaction of 3-substituted 2-siloxyindoles and chiral, enantiopure aldehydes having nitrogen or oxygen substituents at the α carbon

Full text of DOI:10.1021/ol051172+

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