Organic and Biomolecular Chemistry p. 4654 - 4663 (2016)
Update date:2022-08-02
Topics:
Achar, Tapas Kumar
Maiti, Saikat
Mal, Prasenjit
Iodinium cation (I+ or IOAc) was produced from the combination of phenyliodine diacetate (PIDA) and iodine. I+ facilitated the direct vicinal difunctionalization of olefins to α-azido, α-trideuteriomethoxy, α-2,2,2-trifluoroethoxy and α-acyloxy alkyl iodides via cation-π interaction at room temperature and under transition-metal free conditions.
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