INTRAMOLECULAR CYCLOADDITION REACTIONS OF EXOCYCLIC NITRONES APPLICATION IN THE TOTAL SYNTHESIS OF TERPENES

DOI: 10.1016/S0040-4020(01)96702-X

Source and publish data:

Tetrahedron p. 3479 - 3495 (1985)

Update date:2022-08-04

Topics:

Authors:

Funk, Raymond L.

Bolton, Gary L.

Daggett, Joy Umstead

Hansen, Marvin M.

Horcher, Linus H. M.

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Article abstract of DOI:10.1016/S0040-4020(01)96702-X

Exocyclic nitrones smoothly participate in intramolecular cycloaddition reactions to provide bridged and fused polycarbocycles.The exploitation of this methodology in the total syntheses of the sesquiterpenes (+/-)-7,12-secoishwaran-12-ol (44), (+/-)-hirs

Full text of DOI:10.1016/S0040-4020(01)96702-X

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