APPLICATION OF erythro-2-METHOXY-1,2-DIPHENYLETHYLAMINE TO ENANTIOSELECTIVE ALKYLATION OF CYCLOHEXANONE

DOI: 10.1016/S0040-4039(00)81450-1

Source and publish data:

Tetrahedron Letters p. 511 - 512 (1983)

Update date:2022-07-29

Topics:

Authors:

Saigo, Kazuhiko

Kasahara, Atsushi

Ogawa, Shigeo

Nohira, Hiroyuki

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Article abstract of DOI:10.1016/S0040-4039(00)81450-1

The chiral imine, prepared from (-)- or (+)-erythro-2-methoxy-1,2-diphenylethylamine and cyclohexanone, is metalated and alkylated at 0 degC to give the corresponding 2-alkylcyclohexanone in 79-92 optical purity.

Full text of DOI:10.1016/S0040-4039(00)81450-1

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