APPLICATION OF erythro-2-METHOXY-1,2-DIPHENYLETHYLAMINE TO ENANTIOSELECTIVE ALKYLATION OF CYCLOHEXANONE

DOI: 10.1016/S0040-4039(00)81450-1

Source and publish data:

Tetrahedron Letters p. 511 - 512 (1983)

Update date:2022-07-29

Topics:

Authors:

Saigo, Kazuhiko

Kasahara, Atsushi

Ogawa, Shigeo

Nohira, Hiroyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81450-1

The chiral imine, prepared from (-)- or (+)-erythro-2-methoxy-1,2-diphenylethylamine and cyclohexanone, is metalated and alkylated at 0 degC to give the corresponding 2-alkylcyclohexanone in 79-92 optical purity.

Full text of DOI:10.1016/S0040-4039(00)81450-1

Products guided by the article

Product name:(-)-erythro-N-cyclohexylidene-2-methoxy-1,2-diphenylethylamine

Cas No:86448-82-0

R&D Labs maybe for 86448-82-0

SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong
Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China

Relevant to this article

Saponin and Sapogenol. XXXII. Chemical constituents of the seeds of Vigna angularis (Willd.) Ohwi et Ohashi (2). Azukisaponins I, II, III, and IV

Doi:10.1248/cpb.31.674
(1983)
Total synthesis and structural confirmation of (+)-longicin

Doi:10.1021/ol051483k
(2005)
A new approach to the synthesis of oligomers. Application to the synthesis of p-phenylene thioether wires

Doi:10.1016/j.tetlet.2005.06.143
(2005)
Contrasting chemistry of cis- and trans-platinum(II) diamine anticancer compounds: Hydrolysis studies of picoline complexes

Doi:10.1021/ic050763t
(2005)
Towards enzyme-like enantioselectivity in the gas phase: Conformational control of selectivity in chiral macrocyclic dimers

Doi:10.1039/b909017g
(2009)
Regioselective ester cleavage during the preparation of bisphosphonate methacrylate monomers

Doi:10.3762/bjoc.7.46
(2011)

Article Doi