
Organometallics p. 1479 - 1480 (1983)
Update date:2022-08-03
Topics:
Chung, Young Keun
Honig, Ephraim D.
Robinson, Ward T.
Sweigart
Connelly, Nell G.
Ittel, Steven D.
1H NMR and X-ray structural studies show that borohydride addition to dicarbonylnitrosylcyclohexadienylmanganese cations to give cyclohexadiene complexes occurs in a stereospecific endo fashion. This is the first example of stereospecific endo hydride addition to a coordinated cyclic π-hydrocarbon.
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Doi:10.1021/om050568m
(2005)Doi:10.1016/S0040-4020(01)88553-7
(1983)Doi:10.1002/anie.200703665
(2007)Doi:10.1016/S0040-4039(00)81685-8
(1983)Doi:10.1016/0031-9422(86)88028-1
(1986)Doi:10.1021/ja00224a025
(1988)