trans-BIS(DIPHENYLPHOSPHINE)CYCLOPROPANE; A LIGAND SELECTIVE FOR BINUCLEAR COMPLEXATION WITH ca. 4.5 Angstroem INTERMETALLIC SEPARATION

DOI: 10.1016/0022-328X(86)80367-9

Source and publish data:

Journal of Organometallic Chemistry p. 241 - 246 (1986)

Update date:2022-09-26

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Authors:

Brown, John M.

Lucy, Andrew R.

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Article abstract of DOI:10.1016/0022-328X(86)80367-9

trans-1,2-Bis(diphenylphosphinoyl)ethylene was treated with (CH3)2S(CH2) in dimethyl sulphoxide and the product reduced with HSiCl3 to give trans-bis(diphenylphosphino)cyclopropane in 56percent overall yield.The new ligand was found to have a strong affin

Full text of DOI:10.1016/0022-328X(86)80367-9

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