Journal of the American Chemical Society p. 14560 - 14561 (2005)
Update date:2022-08-03
Topics:
Tsang, W. C. Peter
Zheng, Nan
Buchwald, Stephen L.
A new method in which a series of substituted carbazoles is efficiently produced by the combination of an amide and an arene is described. The key feature of this method is the palladium-catalyzed tandem directed C-H functionalization and amide arylation. The method tolerates substitution on either ring of the biaryl amide substrates, and the products can be assembled in a simple two-step protocol from readily available reagents. The Pd(0) species generated are reoxidized to Pd(II) in the presence of Cu(OAc)2 and an atmosphere of oxygen. Copyright
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