Chemistry Letters p. 1085 - 1088 (1983)
Update date:2022-08-03
Topics:
Ogawa, Seiichiro
Inoue, Makoto
Iwasawa, Yoshikazu
A total synthesis of the 6"-epimer of validamycin A and its diastereomer has been accomplished by a coupling reaction of the racemic peracyl 5,6-dihydroxy-1-hydroxymethyl-1,3-cyclohexadiene monoepoxide, the precursor of the unsaturated branched-chain cyclitol portion, with the protected β-D-glucopyranosylvalidamine, followed by acid hydrolysis and O-deacylation.
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Doi:10.1016/j.bmcl.2005.03.039
(2005)Doi:10.1016/j.tet.2005.08.073
(2005)Doi:10.1080/10426500590912259
(2005)Doi:10.1021/jm040903t
(2005)Doi:10.1021/om50006a006
(1983)Doi:10.1021/jm050635e
(2005)
