THERMAL GENERATION OF BIS(TRIMETHYLSILYL)METHYLSILYLENE. REARRANGEMENT OF THE SILYLENE TO A SILAETHYLENE VIA 1,2-SHIFT OF TRIMETHYLSILYL GROUP

DOI: 10.1016/S0040-4039(00)88024-7

Source and publish data:

Tetrahedron Letters p. 2791 - 2794 (1983)

Update date:2022-08-03

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Authors:

Sekiguchi, Akira

Ando, Wataru

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Article abstract of DOI:10.1016/S0040-4039(00)88024-7

The gas phase generation of bis(trimethylsilyl)methyltrimethylsilylsilylene through the pyrolysis of bis(trimethylsilyl)methyl-di-(trimethylsilyl)-methoxysilane yielded a disilacyclobutane via intramolecular C-H insertion and a silaethylene intermediate by 1,2-shift of trimethylsilyl group.

Full text of DOI:10.1016/S0040-4039(00)88024-7

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