Tetrahedron Letters p. 2795 - 2796 (1983)
Update date:2022-07-30
Topics:
Hayama, Takashi
Tomoda, Shuji
Takeuchi, Yoshito
Nomura, Yujiro
The first example of reactivity umpolung of 1-alkenylsilanes has been described.The reaction of trimethyl-(2-nitrovinyl)silane with organometallic compounds regioselectively provided trimethyl-(1-nitromethylalkyl)silanes in excellent yields.
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