Synthesis of 2-exo-Hydroxy-4-thiahomoadamantane and Some Related Derivatives

DOI: 10.1021/jo00170a039

Source and publish data:

Journal of Organic Chemistry p. 4073 - 4076 (1983)

Update date:2022-08-05

Topics:

Authors:

Sasaki, Tadashi

Eguchi, Shoji

Ban, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00170a039

Treatment of 3-endo<(tosyloxy)methyl>-6,7-epoxybicyclo<3.3.1>nonane (2) with sodium sulfide gave 2-exo-hydroxy-4-thiahomoadamantane (4) in good yields.PCC oxidation of 4 afforded the corresponding ketone 9 and 3-thiatricyclo<5.3.1.0^4,9>undec-5-

Full text of DOI:10.1021/jo00170a039

Products guided by the article

Product name:3-endo-<(Tosyloxy)methyl>-6,7-exo-epoxybicyclo<3.3.1>nonane

Cas No:87114-49-6

R&D Labs maybe for 87114-49-6

JIN TAN CHENG'EN CHEMICAL CO.,LTD.

Contact:86-519-82116250

Address:NO.102，village Dongfang，conomic development zone
HANGZHOU GOPHER CHEM-TECH CO.,LTD

Contact:86-189-58111780

Address:Da Cheng Ming Zuo Plaza,Xiaoshan District
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Jiangsu Willing Bio-Tech Co ltd

website:http://www.willingbio.com/

Contact:+86 18796908173

Address:No 18 Guoqiao Road
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China

Relevant to this article

Synthesis of 4-aminoquinazolines by palladium-catalyzed intramolecular imidoylation of N-(2-bromoaryl)amidines

Doi:10.1002/chem.201102468
(2011)
Total synthesis of the interleukin-1β converting enzyme inhibitor EI-1941-2 using tandem oxa-electrocyclization/oxidation

Doi:10.1021/ol060954f
(2006)
Optimized N-phenyl-N′-(2-chloroethyl)ureas as potential antineoplastic agents: Synthesis and growth inhibition activity

Doi:10.1016/j.bmc.2005.07.048
(2005)
High-yield synthesis of warfarin and its phenolic metabolites: New compounds

Doi:10.1002/jps.2600720732
(1983)
Electrosynthesis of pyridines from 'only acetonitrile'

Doi:10.1016/j.tetlet.2005.10.059
(2005)
Convenient Preparation of Bis-Enones and Bis-Enoates from Cycloalkenes

Doi:10.1021/jo00122a066
(1995)

Article Doi