
Journal of Organic Chemistry p. 4073 - 4076 (1983)
Update date:2022-08-05
Topics:
Sasaki, Tadashi
Eguchi, Shoji
Ban, Hiroshi
Treatment of 3-endo<(tosyloxy)methyl>-6,7-epoxybicyclo<3.3.1>nonane (2) with sodium sulfide gave 2-exo-hydroxy-4-thiahomoadamantane (4) in good yields.PCC oxidation of 4 afforded the corresponding ketone 9 and 3-thiatricyclo<5.3.1.04,9>undec-5-
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