SYNTHETIC ENZYMES-4. HIGHLY ENANTIOSELECTIVE EPOXIDATION BY MEANS OF POLYAMINOACIDS IN A TRIPHASE SYSTEM: INFLUENCE OF STRUCTURAL VARIATIONS WITHIN THE CATALYSTS.

DOI: 10.1016/S0040-4020(01)88574-4

Source and publish data:

Tetrahedron p. 1635 - 1642 (1983)

Update date:2022-08-05

Topics:

Authors:

Colonna, Stefano

Molinari, Henriette

Banfi, Stefano

Julia, Sebastian

Masana, Jaume

Alvarez, Angel

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Article abstract of DOI:10.1016/S0040-4020(01)88574-4

The asymmetric epoxidation of chalcone and other electron-poor olefins in a triphase system (water-organic solvent-polyaminoacid) affords optically active oxiranes.The influence of the molecular structure of catalysts and of their secondary conformation on the enantioselectivity of the reaction has also been examined.

Full text of DOI:10.1016/S0040-4020(01)88574-4

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