Journal of Organic Chemistry p. 4219 - 4222 (1983)
Update date:2022-08-03
Topics:
Nelsen, Stephen F.
Parmelee, William P.
Rumack, Daniel T.
Formal oxidation potentials relative to SCE are reported for several cyano-substituted hydrazines and their analogues with the cyano group replaced by a methyl group. ΔE*'was 0.83 V for 2-cyano- and 2-methyl-3-tert-butyl-2,3-diazabicycloheptane (1(CN) and 1(Me)), 0.35 V for trimethyl(cyanomethyl)hydrazine and ethyltrimethylhydrazine (3(CN) and 3(Me)), and 0.23 V for (β-cyanoethyl)trimethylhydrazine and propyltrimethylhydrazine (4(CN) and 4(Me)).The ESR spectrum of 1(CN)-d2 has nitrogen splittings of 17.2 and 7.7 G.The significance of these results is discussed.
Wuhan Yitongtai Science and Technology Co.,Ltd.
Contact:+86-27-88933550
Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Shanghai Haoyuan Chemexpress Co., Ltd.
website:https://www.chemexpress.com/
Contact:86-21-58950125
Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Shanghai Xinda Pharmaceuticals Co., Ltd.
Contact:86-21-33692333-8008
Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Wuhan Chemchemical Co., Ltd.(expird)
Contact:15973022782
Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Shanghai Balmxy Pharmaceutical Co., Ltd
Contact:0086-21-24206007
Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Doi:10.1016/j.bmc.2005.08.036
(2006)Doi:10.1016/j.bmc.2018.04.048
(2018)Doi:10.1002/adsc.201700637
(2017)Doi:10.1021/ja01861a074
(1940)Doi:10.1139/v55-132
(1955)Doi:10.1039/b510910h
(2005)
