THE NORRISH TYPE II PHOTOREACTION OF BENZOYLVALERATES. STEREOCHEMICAL CONTROL IN 1,4-BIRADICAL CYCLIZATION

DOI: 10.1016/S0040-4039(00)81825-0

Source and publish data:

Tetrahedron Letters p. 1995 - 1996 (1983)

Update date:2022-08-05

Topics:

Authors:

Hasegawa, Tadashi

Arata, Yoshiaki

Kageyama, Akihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81825-0

The δ- and β-oxoester 1 and 5 underwent the Type II photoreaction to give the stereoisomeric cyclobutanol 2 and 6, respectively; the ethoxycarbonyl group in the esters determines the stereochemistry of 1,4-biradical cyclization.

Full text of DOI:10.1016/S0040-4039(00)81825-0

Products guided by the article

Product name:ethyl c-2-hydroxy-3,3-dimethyl-2-phenyl-r-1-cyclobutanecarboxylate

Cas No:87362-60-5

R&D Labs maybe for 87362-60-5

ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China

Relevant to this article

Indolactam-V is involved in the CH/π interaction with Pro-11 of the PKCδ C1B domain: Application for the structural optimization of the PKCδ ligand

Doi:10.1021/ja050447d
(2005)
Enantiospecific first total synthesis of (+)-2β-hydroxysolanascone, the aglycone of the phytoalexin isolated from flue-cured tobacco leaves

Doi:10.1016/j.tetlet.2005.11.014
(2006)
Ortho effect in the Bergman cyclization: Interception of p-benzyne intermediate by intramolecular hydrogen abstraction

Doi:10.1021/jo051857n
(2006)
Synthesis of 3-iodoindoles by the Pd/Cu-catalyzed coupling of N,N-dialkyl-2-iodoanilines and terminal acetylenes, followed by electrophilic cyclization

Doi:10.1021/jo051549p
(2006)
Synthesis and evaluation of in vitro antiplatelet aggregation activities of 2-Methoxy-5-Aminobenzamides

Doi:10.2174/1570180816666181128105044
(2019)
Discovery of Indazoles as Potent, Orally Active Dual Neurokinin 1 Receptor Antagonists and Serotonin Transporter Inhibitors for the Treatment of Depression

Doi:10.1021/acschemneuro.6b00337
(2016)

Article Doi