NEW SYNTHESES OF ALLYLSILANES AND VINYLSILANES BY MEANS OF PhMe2Si-AlEt2

DOI: 10.1016/S0040-4039(00)81831-6

Source and publish data:

Tetrahedron Letters p. 2015 - 2018 (1983)

Update date:2022-08-03

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Authors:

Okuda, Yasuhiro

Sato, Mitsuyoshi

Oshima, Koichiro

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(00)81831-6

The reaction of allylic phosphates with the title organoaluminium reagent (PhMe₂Si-AlEt₂) provides allylsilanes in good yields.Cross coupling of enol phosphates with PhMe₂Si-Mtl (Mtl = AlEt₂ or MgMe) produces vi

Full text of DOI:10.1016/S0040-4039(00)81831-6

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