Carbohydrate Research p. 21 - 30 (1983)
Update date:2022-08-04
Topics:
Rasmussen, James R.
Tafuri, Sherrie R.
Smale, Stephen T.
Addition of potassium cyanide to 2-deoxy-2-fluoro-D-arabinose (1) at pH 7.8 followed by catalytic hydrogenation over palladium-barium sulfate (5percent) produced 3-deoxy-3-fluoro-D-glucose (4) and 3-deoxy-3-fluoro-D-mannose (5) in 25 and 40 percent isolated yields, respectively.The epimeric sugars were purified by passage through a column of Dowex-50W x 8 (Ca2+).In a similar manner, 3-deoxy-3-fluoro-D-arabinose (6) was converted into 4-deoxy-4-fluoro-D-glucose (9) and 4-deoxy-4-fluoro-D-mannose (10) in 27 and 45 percent isolated yields, respectively.Deoxyfluorohexoses 4,5,9 and 10 enriched with carbon-13 and crbon-14 at C-1 have been prepared by this procedure.
View MoreSHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD
Contact:+86-311-89871056
Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Heliosense Biotechnologies, Inc.
Contact:+86-592-5667290
Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
WUXI HONOR SHINE CHEMICAL CO.,LTD
Contact:+86-510-83593312
Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY
Contact:0086-0757-85609331
Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
HEZE KINGVOLT CHEMICAL CO., LTD
Contact:86-573-82118911
Address:Juancheng Industry Park
Doi:10.1248/cpb.42.802
(1994)Doi:10.1021/ic051487l
(2006)Doi:10.1016/j.ejmech.2013.10.030
(2013)Doi:10.1002/ejic.201100119
(2011)Doi:10.1021/jf048994q
(2005)Doi:10.1016/j.bmc.2009.01.023
(2009)
