Remote asymmetric trifluoromethylation induced by chiral sulfinyl group: Synthesis of enantiomerically pure 1-(2-naphthyl)-2,2,2-trifluoroethanol

DOI: 10.1016/j.tetlet.2005.12.061

Source and publish data:

Tetrahedron Letters p. 1337 - 1340 (2006)

Update date:2022-08-02

Topics:

Authors:

Sugimoto, Hideki

Nakamura, Shuichi

Shibata, Yoshihiro

Shibata, Norio

Toru, Takeshi

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Article abstract of DOI:10.1016/j.tetlet.2005.12.061

The reaction of 1-[(2,4,6-triisopropylphenyl)sulfinyl]-2-naphthaldehyde with (trifluoromethyl)trimethylsilane using tetramethylammonium fluoride gave trifluoromethylated compounds in high yield with high diastereoselectivity. Desilylation and subsequent r

Full text of DOI:10.1016/j.tetlet.2005.12.061

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