Journal of the Chemical Society. Perkin transactions II p. 1171 - 1174 (1983)
Update date:2022-08-03
Topics:
Abell, Katherine W. Y.
Kirby, Anthony J.
The dianion (8) of bis-2-carboxyphenyl phosphate (half-life 10.2 min at 39 deg C) is hydrolysed ca. 1E10 times faster than diphenyl phosphate.The reaction is accounted for in terms of intramolecular general acid catalysis by the ortho-CO2H of one salicyl group of the breakdown of the penta-covalent intermediate formed by the addition to phosphorus of the carboxylate group of the other.The general acid catalysis part of the process is unexpectedly inefficient.
View MoreHuangshi Shennong Chemical Technology Co., Ltd
Contact:+86-714-3072290
Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China
Jiangxi Lanqi Fine Chemical S&T Co., Ltd.
Contact:+86-21-64891143
Address:XinJiShan Industrial Area, Zhangshu City, JiangXi Province, China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.
Contact:86-716-8331612
Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd
Contact:+86-536-8566856
Address:Shouguang,Shandong,China
Doi:10.1021/ja057745v
(2006)Doi:10.1016/j.molstruc.2005.07.031
(2006)Doi:10.1246/cl.150881
(2016)Doi:10.1039/DT9830001465
(1983)Doi:10.1021/ja056402u
(2006)Doi:10.1016/j.bmcl.2006.08.036
(2006)
