Synthesis, Characterisation, and Catalytic Activity of a Phosphinidene Stabilised Tethered Triruthenium Cluster

DOI: 10.1039/DT9880002649

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2649 - 2654 (1988)

Update date:2022-08-05

Topics:

Authors:

Alexiev, Valentin D.

Binsted, Norman

Cook, Stephen L.

Evans, John

Price, Richard J.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9880002649

A high-yield synthesis of 3-PCH2CH2Si(OEt)3>> (1) from (2) has been developed.This complex can be tethered to high surface area oxide supports.The alumina based material has been characterised by i.r. and u.v.-visible spectroscopies and (31)P cross polarisation magic angle spinning n.m.r., all of which yield comparable data to that obtained for the precursor in solution.Comparison of the chemical shift anisotropy of (1)-alumina with that of a polycrystalline sample of 3-PPh)> (3) is consistent with (1) being firmly tethered to the oxide surface.Ruthenium K-edge extended X-ray absorption fine structure data were obtained for (1) and its alumina tethered version.Analysis of each required two Ru-Ru distances, as expected for the isosceles metal triangle in these complexes.For the tethered complex, these distances were 275(1) and 294(1) pm for the Ru-Ru and Ru-H-Ru units respectively.

Full text of DOI:10.1039/DT9880002649

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Ru₃(CO)11(P(C₆H₅)2H)}

Cas No:87984-98-3

R&D Labs maybe for 87984-98-3

Jiaxing Trustworthy Import And Export Co.,Ltd

Contact:+86-573-82030555

Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Guangxi Shanyun Biochemical Science and Technology Co., Ltd

Contact:+86-0772--6828887

Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Changde Yungang Biotechnology Co., Ltd

website:http://www.cdyg.com

Contact:+86-736-7391178

Address:Qiaonan Industrial Park, Changde City, Hunan Province

Relevant to this article

3. 2. 1.

Doi:10.1021/ja00317a046
(1984)
Synthesis and neuropharmacological evaluation of R(-)-N-alkyl-11- hydroxynoraporphines and their esters

Doi:10.1016/j.bmc.2004.04.029
(2004)
3-Zinciobenzofuran and 3-zincioindole: Versatile tools for the construction of conjugated structures containing multiple benzoheterole units

Doi:10.1002/anie.200502920
(2006)
Discovery of N-aryl-9-oxo-9H-fluorene-1-carboxamides as a new series of apoptosis inducers using a cell- and caspase-based high-throughput screening assay. 2. Structure-activity relationships of the 9-oxo-9H-fluorene ring

Doi:10.1016/j.bmcl.2009.11.025
(2010)
Synthesis and evaluation of human phosphodiesterases (PDE) 5 inhibitor analogs as trypanosomal PDE inhibitors. Part 1. Sildenafil analogs

Doi:10.1016/j.bmcl.2012.01.119
(2012)
Application of a 6π-1-azatriene electrocyclization strategy to the total synthesis of the marine sponge metabolite ageladine A and biological evaluation of synthetic analogues

Doi:10.1021/jo0707232
(2007)

Article Doi