3. 2. 1.

DOI: 10.1021/ja00317a046

Source and publish data:

Journal of the American Chemical Society p. 1461 - 1467 (1984)

Update date:2022-08-05

Topics:

Authors:

Bridges Bridges

Raman Raman

Jones Jones

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Article abstract of DOI:10.1021/ja00317a046

Preparative-scale horse liver alcohol dehydrogenase catalyzed oxidations of meso-1,3-bis(hydroxymethyl)cyclopentyl and -cyclohexyl substrates proceed stereospecifically to give 42-81% yields of the corresponding chiral bridged-bicyclic gamma -lactones of 100% ee. For each diol, oxidation of the hydroxymethyl group attached to the S center occurs exclusively. The stereospecificities observed are as predicted by the active-site model of the enzyme.

Full text of DOI:10.1021/ja00317a046

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