Structural Studies on Mixed Iron-Gold Clusters with Bidentate Tertiary Phosphine Ligands

DOI: 10.1039/c39830000843

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 843 - 845 (1983)

Update date:2022-08-02

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Authors:

Briant, Clive E.

Hall, Kevin P.

Mingos, D. Michael P.

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Article abstract of DOI:10.1039/c39830000843

Structural analyses on 2 (1a) and 2 (1b) have demonstrated that the bite angle of the phosphine ligands exerts a profound influence on the cluster geometry, since (1a) has a rhomboid of gold atoms with μ₂-Fe(CO)4 moieties, and (1b) has well separated Au2Fe triangles.

Full text of DOI:10.1039/c39830000843

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