Synthesis and Characterization of a Dimeric Hydridorhodacarbaborane Anion Derived from the nido-Monocarbaborane, B10H12CNH3

DOI: 10.1039/c39830000803

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 803 - 804 (1983)

Update date:2022-08-02

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Authors:

Walker, John A.

O'Con, Conrad A.

Zheng, Limin

Knobler, Carolyn B.

Hawthorne, M. Frederick

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Article abstract of DOI:10.1039/c39830000803

The reaction of RhCl(PPh3)3 with nido-B10H12CNH3 in the presence of Buⁿ4NOH produced n4N>, which upon heating in methanol produced a new orange compound confirmed by an X-ray diffraction study to be the n4N>+ salt of an -NH2-bridged Rh-H-Rh dimer anion.

Full text of DOI:10.1039/c39830000803

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