Preparation and Rearrangement of trans-3-(Allyloxy)acrylic Acids: A Claisen Sequence That Avoids Mercury Catalysis

DOI: 10.1021/jo00174a064

Source and publish data:

Journal of Organic Chemistry p. 5406 - 5408 (1983)

Update date:2022-07-30

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Authors:

Buechi, George

Vogel, Dennis E.

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Article abstract of DOI:10.1021/jo00174a064

Reaction of sodium or lithium salts of primary and secondary allylic alcohols with (E)-(carboxyvinyl)trimethylammonium betaine affords (E)-3-(allyloxy)acrylic acids, which on heating are transformed to γ,δ-unsaturated aldehydes.

Full text of DOI:10.1021/jo00174a064

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