Tetrahedron Letters p. 3269 - 3272 (1983)
Update date:2022-08-03
Topics:
Gilmore, Christopher J.
MacNicol, David D.
Murphy, Anthony
Russell, Marie A.
Hexakis(aryloxy)benzenes (I)-(IV), representatives of a new class of molecule, have been prepared by reaction of hexafluorobenzene with the sodium salt of the appropriate phenol in 1,3-dimethyl-2-imidazolidinone (DMEU) as solvent.X-ray analyses of parent (I) and of the acetonitrile clathrate of (II) are described, a novel edge-on interaction between host and guest being found in the latter.
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