Journal of the Chemical Society. Perkin transactions II p. 993 - 996 (1983)
Update date:2022-07-29
Topics:
Renzi, Augusto De
Panunzi, Achille
Saporito, Antonio
Vitagliano, Aldo
1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes.A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans.Possible reaction mechanisms are also discussed.
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