PREPARATION AND CARBONYL ADDITION OF γ,γ-DIFLUOROALLYLSILANES

DOI: 10.1016/S0040-4039(00)88275-1

Source and publish data:

Tetrahedron Letters p. 4113 - 4116 (1983)

Update date:2022-08-04

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Authors:

Hiyama, Tamejiro

Obayashi, Michio

Sawahata, Miwa

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Article abstract of DOI:10.1016/S0040-4039(00)88275-1

The reaction of 3,3,3-trifluoropropenes with disilane/tetrabutylammonium fluoride or silyllithium reagent gives γ,γ-difluoroallylsilanes which afford gem-difluoroallyl adducts of aldehydes and ketones with the aid of a catalyst such as potassium t-butoxid

Full text of DOI:10.1016/S0040-4039(00)88275-1

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