Helvetica Chimica Acta p. 2223 - 2235 (1983)
Update date:2022-08-03
Topics:
Maurer, Bruno
Hauser, Arnold
Six sesquiterpenoids, (2R,5E)-2,12-epoxycaryophyll-5-ene (1), (2R,5E)-caryophyll-5-en-12-al (2), (2S,5E)-caryophyll-5-en-12-al (3), isospathulenol (4), (1R,5R)-1,5-epoxysalvial-4(14)-ene (5), and salvial-4(14)-en-1-one (6) have been identified for the first time in clary sage oil (Salvia sclarea L.).The structures and absolute configurations of 1-6 are corroborated by partial syntheses and their organoleptic properties are discussed.The compounds 5, 6 and mintsulfide (14) possess the rare C-skeleton C, for which the semisystematic name 'salvialane' is proposed.The sesquiterpenoids 1-5 are new.
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